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DE NOVO SYNTHESIS OF MESOPOROUS PHOTOACTIVE TITANIUM(IV)-ORGANIC FRAMEWORKS WITH MIL-100 TOPOLOGY

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Javi reports the synthesis of the first mesoporous titanium-organic framework, now available in Chemical Science. The use of High-Throughput (HT) methodologies enabled the synthesis of highly crystalline MIL-100(Ti). Compared to the classical Fe phase, this MOF shows improved chemical stability and retains the photoactivity intrinsic to Ti(IV) centers. Photocatalytic H2 production was demonstrated in collaboration with Hermenegildo García’s group at the Instituto of Tecnología Química. For more details check the link