MOF School held in Lake Como (Italy) with an amazing line up of invited speakers and presented her recent work on the nanosizing of titanium frameworks and photoactive Zr(IV) MOFs. They also had time to make new friends!
See here for more info.
Carlos visited KU Leuven (Prof. Dirk De Vos and Francisco García Cirujano) to present the last results of the team on charge transport and photoactivity in MOFs.
Funimat was present at the International Symposium on Composites of Metal and Covalent Organic Frameworks held in Granada. Carlos delivered a keynote lecture on Charge Transport in Ultrathin films of Metal-Organic Framewors. For more details see here.
Fran is originally from Elche. He joins the team with a La Caixa Junior Leader Fellowship Fellowship after a Postdoc stay in KU Leuven with Dirk De Vos. He will focus on the development of high performance metal-organic framework catalysts.
Ana graduated in Chemistry in 2018 after an Erasmus stay at The University of Manchester. She will be exploring new methodologies for the flow synthesis of pharmaceuticals with MOF catalysts.
Rubén graduated in Chemistry at the Universidad de Valencia in 2019. He will be exploring the electrocatalytic properties and potential of some of the materials developed @FuniMAT in energy conversion.
Alejandros work has just been published in Angewandte Chemie Int. Ed. In this paper, Single-Crystal X-Ray Diffraction is used to follow the restricted polymerization of pyrrole inside a cyclodextrin MOF, which generates discrete units of highly reactive cationic terpyrrole inside the pores. This work gives unprecedented information about the host-guest interactions that limit the formation of polymers, that can be useful to future works using MOFs as templates for polymerization processes. For more info see here
Javi reports the synthesis of the first mesoporous titanium-organic framework, now available in Chemical Science. The use of High-Throughput (HT) methodologies enabled the synthesis of highly crystalline MIL-100(Ti). Compared to the classical Fe phase, this MOF shows improved chemical stability and retains the photoactivity intrinsic to Ti(IV) centers. Photocatalytic H2 production was demonstrated in collaboration with Hermenegildo Garcías group at the Instituto of Tecnología Química. For more details check the link
On a recently published joint work, Jose, Neyvis and Belén used a novel method to induce the translocation of an enzyme into the pores of a MOF. Their procedure is based in a partial denaturation of the enzyme followed by its refolding into the polar cavities offered by the host. Thanks to a combination of experimental and theoretical work, we managed to demonstrate that the enzyme adopts a different conformation inside the MOF, granting it enhanced activity, stability and recyclability. The work is now available in Chemical Science
Víctors study on the nanostructuration of spin crossover coordination polymers has just been published in Chemical Science. A collaborative endeavor with contributions from FuniMat, RTMM and SMolMat groups of the ICMol, together with Unité Mixte de Physique CNRS/Thales and DEIMOS beamline of the Soleil synchrotron. Below a critical thickness, the completeness of the spin transition is sharply affected due to an equally dramatic film microstructure transition from fully coalesced layer into segregated nanocrystalline particles. This careful examination of the spin crossover properties of films at the nanoscale provides relevant information for scientists working towards the integration of this switchable materials into nanometric electronic and spintronic devices. For more details take a look at the full text here