This chapter explores metal-based catalysis within metal-organic frameworks (MOFs). It aims to offer readers a comprehensive understanding of various strategies…
We recently reported the possibility of using the heterometallic Ti Cluster [Ti2Ca2(µ3-O)2(RCO2)8(H2O)4] (Ti2Ca2) to assemble two isoreticular the nets: MUV-10…
This work combines novel techniques such as photo thermal induced resonance (PTIR) and hyperspectral photoluminescence (PL) microscopy to study in…
The manuscript illustrates the value of tetrazine units to wrap up the surface of UiO-68-TZDC crystals with a single-wall carbon…
Ana’s work has been published in JACS. In this work, we use the cluster composition to control the Brønsted acidic character of titanium-organic frameworks ultimately leading to great implications in catalysis.
Belen´s work has been published in JACS. The manuscript describes the use of hydroxamate linkers for the assembly of titanium-organic cages with permanent porosity (near 1200 m2·g-1) that are also amenable to multivariate modification.
Our collaboration with David Écija´s lab at IMDEA Nanoscience has been published in JACS. The wok describes how the use of conductive surfaces to template the growth of 2D networks based on HTTP linkers enables to obtain unprecedented 2D topologies that preserve a large orbital magnetic moment.
The recent work by Belén and Carol has been published in Angewandte Chemie. The manuscript demonstrates the general value of tetrazine linkers as plug-and-play tags for general framework functionalization in one-step and how this ligation strategy can be can useful to produce crystalline fulleretic materials by controlling the spatial distribution of C60 molecules in the framework.
This manuscript by Isabel has been published in Chemical Science. The manuscript shows the value of integrating experimental work, computational modelling and thorough characterization in rationalizing the impact of defects over the porosity and structure of the titanium framework MUV-10. Click for more info.
Maria´s work has been published in Chemical Communications. The work is focused on the use of amphiphilic modulators to control the formation of titanium MOF nanoparticles with minimum impact to the framework to enable the fabrication of highly porous thin films. Click for more info.