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23 Abr: Welcome to metal-induced Dynamic topological transformations

Natalia and Belen’s work has been published in JACS. Their work introduces a pioneering methodology for the synthesis of heterometallic titanium frameworks amenable to the principles of reticular chemistry. Instead of relying in the serendipitous discovery of mixed-metal clusters by trial and error, we use heterometallic MOF crystals as precursors to direct the formation of SBUs with variable connection points by metal exchange reactions at low temperature. Click for more info

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23 Abr: Shaping and growing peptide MOF crystals

We are really happy to see our collaboration with Puigmartí-Luis group published in JACS. By using microfluidic chips we manage to grow and shape crystals of our beloved Cu(GHG) peptide MOF at the millimeter scale. This approach permits generating monolith single crystals and might help overcoming the problems associated with the pelletization and densification of these materials for their successful implementation into functional devices. Click for more info

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04 Oct: HELLO TO HYDROXAMATE FRAMEWORKS

Natalia´s work is already available at JACS. The design of metal–organic frameworks with chemical stability is limited to metal connectors as carboxylates or azolates. Inspired by the chemistry of siderophores, we report a hydroxamate titanium framework that combines photoactivity with hydrolytic stability. The straightforward derivatization of carboxylic linkers with hydroxamic groups might represent an alternative route to broaden the family of reticular solids. Check it out!

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04 Oct: CHIRAL MOFs FOR AFFORDABLE CHIRAL CHROMATOGRAPHY

Our work in collaboration with J.R. Galan-Mascaros’ group at ICIQ has been published in JACS. This work highlights the versatility and efficiency of TAMOF-1 as a chiral stationary phase capable of separating a variety of model racemic mixtures, including drugs, in a wide range of solvents of different polarity. This performance arises from the combination of chiral channels and weak binding sites allowing for low-energy separation of enantiomers, without any strong binding/recognition sites. Click for more info