Javi reports the synthesis of the first mesoporous titanium-organic framework, now available in Chemical Science. The use of High-Throughput (HT) methodologies enabled the synthesis of highly crystalline MIL-100(Ti). Compared to the classical Fe phase, this MOF shows improved chemical stability and retains the photoactivity intrinsic to Ti(IV) centers. Photocatalytic H2 production was demonstrated in collaboration with Hermenegildo Garcías group at the Instituto of Tecnología Química. For more details check the link
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Alejandros work has just been published in Angewandte Chemie Int. Ed. In this paper, Single-Crystal X-Ray Diffraction is used to follow the restricted polymerization of pyrrole inside a cyclodextrin MOF, which generates discrete units of highly reactive cationic terpyrrole inside the pores. This work gives unprecedented information about the host-guest interactions that limit the formation of polymers, that can be useful to future works using MOFs as templates for polymerization processes. For more info see here
Katherine Mirica (Dartmouth College) visited us and presented the recent advances of her team on conductive metal-organic frameworks to develop advanced sensory platforms. We are hopeful this will initiate a fruitful collaboration between both groups.
Victor has officially become Dr. Rubio-Giménez after defending his PhD Thesis. The jury was formed by Prof. Mirica, Medina and Gándara. Victor will continue his work on conductive and magnetic MOFs until September 2019 when he will join Ameloot´s group at Leuven with a FWO Fellowship. Congratulations!
Isabel and Francisco have been awarded the Marie Curie and La Caixa Junior Leader Fellowships, respectively. These are very competitive calls that highlight their excellent scientific and academic performance. Congratulations!
Carlos joined Yaghi´s lab at UC Berkeley as a visiting scholar to discuss on potential collaborations on water adsorption and CO2 reduction with heterometallic titanium organic frameworks. Thanks for the invitation!
FuniMAT was present at the International Symposium Polymat-Spotlight devoted to 2D and Porous Polymers. Carlos delivered a keynote lecture on Charge Transport in Ultrathin films of Metal-Organic Frameworks
Kim Jelfs (Imperial College of London) and Martijn Zwijnenburg (University College London) visited us to lecture on the recent advances of their teams on the modelling of porous cages and high-throughput screening pf polymer photocatalysts. We are hopeful this will initiate a fruitful collaboration between both groups.
MOF ultrathin films. Victor presented our recent work on spin-crossover materials at the nanoscale. For more details see here
Carlos visited the Universidad de Granada (Prof. Jorge A. R. Navarro) to present our research on lateral and vertical charge-transport in ultrathin MOF films.