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10 Jun: Heterometallic titanium frameworks for unlocking mixed oxides

Javi´s work during his stay in KAUST in J. Gascón´s group has been published in Chem Catalysis. The work illustrates the exciting possibilities offered by MUV-101(Fe) for the production of catalytic materials not accessible through traditional synthetic routes and opens the door to translating the atomic control of metal composition and distribution of the parent MOF onto complex mixed-oxide structures with industrial applications. Check the web for more info.

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10 Jun: Selective implantation of amines in heterometallic MOFs

Elena’s work has been published as “hot paper” in Angewandte. Her work introduces the first example of isoreticular titanium–organic frameworks, MUV-10 and MUV-12, to show how the different affinity of hard Ti(IV) and soft Ca(II) metal sites can be used to direct selective grafting of amines for cooperative cycloaddition of CO2 to epoxides at room temperature and atmospheric pressure. Check the web for more info.

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08 Ene: Promoting defectivity in titanium-organic frameworks

Isabel’s work has been published in Chemical Science. Her work shows the ability of isophthalic to promote defect creation in the heterometallic Ti-MOF of the MUV-10 family. Compared to monocarboxylic acids, this bidentate linker permits compensating the structural distortion and energy penalty imposed by breaking the connectivity of the underlying framework. Click for more info